Photothermal Diffusivity

Infer thermal diffusivity from photothermal-wave phase lag at a known offset.

Description

A photothermal phase model estimates diffusivity from modulation frequency, offset and phase lag.

A photothermal phase model estimates diffusivity from modulation frequency, offset and phase lag. The supplied lag is assumed to follow the chosen diffusion relation.1

Infer thermal diffusivity from photothermal-wave phase lag at a known offset.

When to use Photothermal Diffusivity

Use this tool to infer thermal diffusivity from photothermal-wave phase lag at a known offset.

Prepare the optical measurements, geometry, fitted coefficients or caller-selected thresholds requested. Confirm wavelength, radius/diameter, pulse-width, angle and unit conventions before running the calculation.

How to use Photothermal Diffusivity and understand its results

  1. Prepare the optical measurements, geometry, fitted coefficients or caller-selected thresholds requested. Confirm wavelength, radius/diameter, pulse-width, angle and unit conventions before running the calculation.
  2. Enter modulationFrequencyHertz, measurementOffsetMeters, phaseLagRadians using the field table and calculation rules, then run the tool.
  3. Read thermalDiffusivitySquareMetersPerSecond. The explanation below defines the units, signs, ordering and any flags or placeholder values.
  4. If the tool reports an input issue, correct the values and run it again. Apply the stated assumptions when interpreting a successfully returned result.
Input fieldMeaningValue type; see rules belowRequirement
modulationFrequencyHertzModulation frequency (Hz)number; minimum: 0Required
measurementOffsetMetersMeasurement offset (m)number; minimum: 0Required
phaseLagRadiansThermal-wave phase lag (rad)number; minimum: 0Required

Enter nonnegative frequency/offset and positive phase lag in radians. Return m²/s.

diffusivity=πfrequency×offset²/phaseLag²

Units, indexing, boundary conditions and exceptional cases are defined in the calculation rules above.

Output fieldMeaningValue type
thermalDiffusivitySquareMetersPerSecondThermal diffusivity (m²/s)number; minimum: 0
json
{
  "input": {
    "modulationFrequencyHertz": 1,
    "measurementOffsetMeters": 0.001,
    "phaseLagRadians": 3.141592653589793
  },
  "output": {
    "thermalDiffusivitySquareMetersPerSecond": 3.1830988618379064e-7
  }
}

Limitations and assumptions

No phase fitting, layered geometry, boundary conditions or material validation is performed.

Numeric inputs must be finite. Follow the calculation-specific rules for overflow, underflow and exceptional cases. Missing required fields, extra fields, wrong value types and violations of the calculation rules are input errors.

Alternative or Complementary methods

Use Nanorod Heating Estimate: Estimate adiabatic sample heating from absorbed nanorod illumination. For a complementary task, use Thermal-Lens Coefficient: Calculate measured thermal-lens dioptric-power change per watt of pump-power change.

References

  1. Photothermal Diffusivity — tool.io

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