Annealing Thermal Budget

Convert an annealing step to an Arrhenius-equivalent thermal budget.

Description

Arrhenius equivalent time compares process temperature with a reference using an activation energy.

Arrhenius equivalent time compares process temperature with a reference using an activation energy. It assumes the same thermally activated process at both temperatures.1

Convert an annealing step to an Arrhenius-equivalent thermal budget.

When to use Annealing Thermal Budget

Use this tool to convert an annealing step to an Arrhenius-equivalent thermal budget.

Prepare the optical measurements, geometry, fitted coefficients or caller-selected thresholds requested. Confirm wavelength, radius/diameter, pulse-width, angle and unit conventions before running the calculation.

How to use Annealing Thermal Budget and understand its results

  1. Prepare the optical measurements, geometry, fitted coefficients or caller-selected thresholds requested. Confirm wavelength, radius/diameter, pulse-width, angle and unit conventions before running the calculation.
  2. Enter processTemperatureKelvin, processSeconds, referenceTemperatureKelvin, activationEnergyEv using the field table and calculation rules, then run the tool.
  3. Read rateRatioToReference, equivalentReferenceSeconds. The explanation below defines the units, signs, ordering and any flags or placeholder values.
  4. If the tool reports an input issue, correct the values and run it again. Apply the stated assumptions when interpreting a successfully returned result.
Input fieldMeaningValue type; see rules belowRequirement
processTemperatureKelvinProcess temperature (K)number; minimum: 0Required
processSecondsProcess duration (s)number; minimum: 0Required
referenceTemperatureKelvinReference temperature (K)number; minimum: 0Required
activationEnergyEvActivation energy (eV)number; minimum: 0Required

Enter positive kelvin temperatures and nonnegative seconds/activation eV. Use kB=8.617333262145e−5 eV/K. Return ratio and reference-equivalent seconds.

rateRatio=exp(−Ea/kB×(1/Tprocess−1/Tref)); equivalentTime=time×ratio

Units, indexing, boundary conditions and exceptional cases are defined in the calculation rules above.

Output fieldMeaningValue type
rateRatioToReferenceArrhenius rate rationumber; minimum: 0
equivalentReferenceSecondsEquivalent reference-temperature time (s)number; minimum: 0
json
{
  "input": {
    "processTemperatureKelvin": 1000,
    "processSeconds": 10,
    "referenceTemperatureKelvin": 1000,
    "activationEnergyEv": 1
  },
  "output": {
    "rateRatioToReference": 1,
    "equivalentReferenceSeconds": 10
  }
}

Limitations and assumptions

No temperature ramp, reaction mechanism, prefactor change or material validation is supplied.

Numeric inputs must be finite. Follow the calculation-specific rules for overflow, underflow and exceptional cases. Missing required fields, extra fields, wrong value types and violations of the calculation rules are input errors.

Alternative or Complementary methods

Use Ablation Threshold Fit: Fit a Liu ablation-threshold line from pulse energy and squared crater radius. For a complementary task, use Photothermal Diffusivity: Infer thermal diffusivity from photothermal-wave phase lag at a known offset.

References

  1. Annealing Thermal Budget — tool.io

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