Exciton Binding Energy Calculator

Compute the 3D hydrogenic Wannier-Mott exciton ground-state binding energy from reduced electron-hole mass and relative permittivity.

Description

Estimate the ground-state binding energy of a three-dimensional hydrogenic Wannier-Mott exciton from reduced electron-hole mass and dielectric screening.

Compute the 3D hydrogenic Wannier-Mott exciton ground-state binding energy from reduced electron-hole mass and relative permittivity.

When to use Exciton Binding Energy Calculator

  • Estimate the ground-state binding energy of a three-dimensional hydrogenic Wannier-Mott exciton from reduced electron-hole mass and dielectric screening.
  • Compare fabrication or device scenarios while holding coefficients and unit conventions constant.
  • Check a hand calculation before moving to a higher-fidelity process, circuit, or TCAD model.

How the calculation works

Binding energy grows linearly with reduced mass and falls with the square of relative permittivity. The unscreened εr = 1 case is mathematically valid, and the model does not impose an artificial upper bound of one on µ/m0.

Eb = Ry · (µ/m0) / εr²

Interpreting the result

Binding energy grows linearly with reduced mass and falls with the square of relative permittivity. The unscreened εr = 1 case is mathematically valid, and the model does not impose an artificial upper bound of one on µ/m0.

Assumptions and limitations

  • The result assumes isotropic parabolic bands, a bulk 3D Coulomb potential, and spatially uniform dielectric screening. Two-dimensional materials, nonlocal screening, mass anisotropy, central-cell effects, polaronic screening, and uncertainty over static versus optical permittivity can produce non-hydrogenic binding energies.
  • Use parameters measured for the same material, geometry, temperature, and operating regime whenever the result informs engineering work.
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