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Isotope Standard Delta Residual Tool

Compare a supplied isotope delta notation to a supplied positive standard ratio without choosing isotope standards.

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Description

Compute delta as 1000 times (sample ratio divided by standard ratio minus one), then return reported minus derived delta as the residual.

An isotope ratio depends on which isotope is in the numerator and denominator. Delta notation compares a ratio with a reference on a per-mil scale, while mixing and decay models require explicit amount and system assumptions.

Compute delta as 1000 times (sample ratio divided by standard ratio minus one), then return reported minus derived delta as the residual.

When to use this tool

Use Isotope Standard Delta Residual when you need a stated isotope-reference, mixing, or one-step decay calculation.

How to use the tool and how it works

  1. Enter sampleRatio, suppliedStandardRatio, reportedDeltaPerMil. Use the units and conventions below.
  2. Run the tool. Correct any format, range, or cross-field input error before interpreting the output.
  3. Read derivedDeltaPerMil, residualPerMil. Use the output convention below.

Require nonnegative sampleRatio and positive suppliedStandardRatio. Compute delta as 1000 times (sample ratio divided by standard ratio minus one), then return reported minus derived delta as the residual.1

Delta notation reports 1000(sample ratio/reference ratio−1), in per mil rather than percent.2

Input fieldMeaning and unitsAccepted input
sampleRatioSample RatioRequired. Finite number; minimum 0.
suppliedStandardRatioSupplied Standard RatioRequired. Finite number; strictly above 0.
reportedDeltaPerMilReported Delta Per MilRequired. Finite number.
Output fieldInterpretationReturned shape
derivedDeltaPerMilDerived Delta Per MilRequired. Finite number.
residualPerMilResidual Per MilRequired. Finite number.
json
{
  "input": {
    "sampleRatio": 1.1,
    "suppliedStandardRatio": 1,
    "reportedDeltaPerMil": 90
  },
  "output": {
    "derivedDeltaPerMil": 100.00000000000009,
    "residualPerMil": -10.000000000000085
  }
}

Limitations and assumptions

  • Isotope ratios must use the same numerator/denominator orientation and the deltas are per mil. No isotope standard, fractionation correction, measurement uncertainty, or laboratory calibration is selected.
  • Inputs must satisfy both the field types and the cross-field conditions above. Invalid input causes an error; a successful false flag or documented placeholder is a different result.
  • Numeric calculations use binary floating point unless exact decimal-integer arithmetic is explicitly stated. No hidden measurement tolerance or decimal rounding is added; nonfinite or out-of-contract results are rejected. Numeric signed-zero results are exported as zero.

Alternative or Complementary methods

Use the appropriate reference materials and full isotope model for interpretation. Preserve ratio orientation, reference scale, denominator-isotope weighting, uncertainty, and any open-system or fractionation effects.

References

  1. Calculation and input contract: geochemistry/isotope-standard-delta-residual — tool.io

  2. Fundamentals of Isotope Geochemistry: delta notation — USGS, Kendall and Caldwell

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