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Levich Rotation Two Thirds Factor Tool

Levich transport factor D^(2/3) nu^(-1/6) omega^(1/2); rotation is radians per time unit, with a supplied convention-specific coefficient.

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Description

Calculate a Levich-style transport factor with diffusivity to the two-thirds power and square-root angular-speed dependence.

Electrochemical current and potential terms depend on reaction direction, transport geometry and a declared reference state. Named equations apply under specific kinetic or diffusion assumptions; one scaling factor is not a full electrochemical model.

Calculate a Levich-style transport factor with diffusivity to the two-thirds power and square-root angular-speed dependence.

When to use this tool

Use Levich Rotation Two Thirds Factor when checking one supplied kinetic or transport-model contribution.

How to use the tool and how it works

  1. Enter diffusivity, kinematicViscosity, angularSpeed, coefficient. Use the units and conventions below.
  2. Run the tool. Correct any format, range, or cross-field input error before interpreting the output.
  3. Read transportFactor. Use the output convention below.

Require positive diffusivity, kinematicViscosity and coefficient and nonnegative angularSpeed. transportFactor = coefficient*diffusivity^(2/3)*kinematicViscosity^(-1/6)*sqrt(angularSpeed).1

The Levich transport dependence uses diffusivity to the two-thirds power, viscosity to the minus-one-sixth power and a square root of rotation. Prefactors depend on units.2

Input fieldMeaning and unitsAccepted input
diffusivityDiffusivityRequired. Finite number; strictly above 0.
kinematicViscosityKinematic ViscosityRequired. Finite number; strictly above 0.
angularSpeedNonnegative angular speed in radians per time unit; choose coefficient units consistently, and convert RPM separately.Required. Finite number; minimum 0.
coefficientPositive prefactor with units compatible with diffusivity, viscosity and rotation convention.Required. Finite number; strictly above 0.
Output fieldInterpretationReturned shape
transportFactorTransport FactorRequired. Finite number.
json
{
  "input": {
    "diffusivity": 1e-9,
    "kinematicViscosity": 0.000001,
    "angularSpeed": 100,
    "coefficient": 0.62
  },
  "output": {
    "transportFactor": 0.00006200000000000004
  }
}

Limitations and assumptions

  • The angular-speed exponent is one-half despite the tool name's two-thirds wording; two-thirds applies to diffusivity. Supply angular speed in the coefficient's convention, not RPM without conversion. Other Levich factors are not automatically included.
  • Inputs must satisfy both the field types and the cross-field conditions above. Invalid input causes an error; a successful false flag or documented placeholder is a different result.
  • Numeric calculations use binary floating point unless exact decimal-integer arithmetic is explicitly stated. No hidden measurement tolerance or decimal rounding is added; nonfinite or out-of-contract results are rejected. Numeric signed-zero results are exported as zero.

Alternative or Complementary methods

Use a suitable complete model and verified experimental conditions before interpreting a local term as mechanism, performance or a fitted parameter.

References

  1. Calculation and input contract: electrochemistry/levich-rotation-two-thirds-factor — tool.io

  2. Terminology of electrochemical methods of analysis: 2019 provisional recommendation — IUPAC

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