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Crystallization Solubility Cooling Yield Term Tool

Solubilities are solute mass per solvent mass, with no solvent evaporation or hydrate formation.

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Description

Return a cooling-crystallization mass-yield term.

A process stream can be described on mass, mole, phase or solvent bases, which are not interchangeable. Lever rules, partition factors and operating-line terms assume compatible composition definitions and an appropriate physical model; a local balance does not determine equilibrium properties or a complete separation design.

Return a cooling-crystallization mass-yield term.

When to use this tool

Use Crystallization Solubility Cooling Yield Term when checking the stated stream composition, phase or separation-model term.

How to use the tool and how it works

  1. Enter solventMass, initialSolubility, finalSolubility, crystalRecovery. Use the units and conventions below.
  2. Run the tool. Correct any format, range, or cross-field input error before interpreting the output.
  3. Read theoreticalCrystalMass, recoveredCrystalMass, dissolvedRemaining. Use the output convention below.

Return a cooling-crystallization mass-yield term. Require solventMass >= 0 and initialSolubility >= finalSolubility >= 0, recovery in [0,1]; theoretical crystals = solvent*(initial-final), recovered multiplies recovery, dissolved remaining = solvent*final.1

Input fieldMeaning and unitsAccepted input
solventMassSolvent MassRequired. Finite number; minimum 0.
initialSolubilityInitial solute mass per solvent mass, not per total solution mass.Required. Finite number.
finalSolubilityFinal solute mass per solvent mass on the same basis.Required. Finite number; minimum 0.
crystalRecoveryCrystal RecoveryRequired. Finite number; minimum 0; maximum 1.
Output fieldInterpretationReturned shape
theoreticalCrystalMassTheoretical Crystal MassRequired. Finite number.
recoveredCrystalMassRecovered Crystal MassRequired. Finite number.
dissolvedRemainingDissolved RemainingRequired. Finite number.
json
{
  "input": {
    "solventMass": 100,
    "initialSolubility": 0.5,
    "finalSolubility": 0.2,
    "crystalRecovery": 0.8
  },
  "output": {
    "theoreticalCrystalMass": 30,
    "recoveredCrystalMass": 24,
    "dissolvedRemaining": 20
  }
}

Limitations and assumptions

  • Solubilities are solute mass per solvent mass, not solution mass fractions; solvent loss and actual phase equilibrium are not modeled.
  • Inputs must satisfy both the field types and the cross-field conditions above. Invalid input causes an error; a successful false flag or documented placeholder is a different result.
  • Numeric calculations use binary floating point unless exact decimal-integer arithmetic is explicitly stated. No hidden measurement tolerance or decimal rounding is added; nonfinite or out-of-contract results are rejected. Numeric signed-zero results are exported as zero.

Alternative or Complementary methods

Use verified equilibrium and material-property data on consistent bases and solve the complete process model for actual separation or equipment decisions.

References

  1. Calculation and input contract: chemical-engineering/crystallization-solubility-cooling-yield-term — tool.io

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