Atmospheric Blank Subtraction Uncertainty Term Tool

Description

Return separately normalized sample/blank concentration and uncertainty.

Standard uncertainties combine through the measurement model and the covariance of its inputs. Correlated errors may reinforce or cancel, and treating a scale or volume as exact is a substantive assumption. A propagated value is different from a complete uncertainty budget or a statistical decision.

Return separately normalized sample/blank concentration and uncertainty.

When to use this tool

Use Atmospheric Blank Subtraction Uncertainty Term when checking the stated uncertainty-propagation term under supplied correlation and exact-input assumptions.

How to use the tool and how it works

Enter sampleAmount, blankAmount, sampleVolume, blankEquivalentVolume, sampleUncertainty, blankUncertainty. Use the units and conventions below.
Run the tool. Correct any format, range, or cross-field input error before interpreting the output.
Read correctedConcentration, combinedUncertainty. Use the output convention below.

Return separately normalized sample/blank concentration and uncertainty. Require positive sample/blank-equivalent volumes and nonnegative amount uncertainties; corrected = sampleAmount/sampleVolume-blankAmount/blankVolume, combined uncertainty is hypot(uSample/sampleVolume,uBlank/blankVolume).^[1]

Uncertainty propagation depends on the measurement model and input covariance. Omitting correlations or treating volume as exact requires justification; this helper is only one specified contribution.^[2]

Input field	Meaning and units	Accepted input
sampleAmount	Sample Amount	Required. Finite number.
blankAmount	Blank Amount	Required. Finite number.
sampleVolume	Sample Volume	Required. Finite number; strictly above 0.
blankEquivalentVolume	Blank Equivalent Volume	Required. Finite number; strictly above 0.
sampleUncertainty	Standard uncertainty of sampleAmount, not of concentration or sampled volume.	Required. Finite number; minimum 0.
blankUncertainty	Standard uncertainty of blankAmount; treated independent of sample uncertainty.	Required. Finite number; minimum 0.

Output field	Interpretation	Returned shape
correctedConcentration	Corrected Concentration	Required. Finite number.
combinedUncertainty	Combined Uncertainty	Required. Finite number.

json

{
  "input": {
    "sampleAmount": 10,
    "blankAmount": 2,
    "sampleVolume": 2,
    "blankEquivalentVolume": 2,
    "sampleUncertainty": 0.6,
    "blankUncertainty": 0.8
  },
  "output": {
    "correctedConcentration": 4,
    "combinedUncertainty": 0.5
  }
}

Limitations and assumptions

This assumes independent amount uncertainties and exact volumes; correlations, volume uncertainty and a complete analytical uncertainty budget are omitted.
Inputs must satisfy both the field types and the cross-field conditions above. Invalid input causes an error; a successful false flag or documented placeholder is a different result.
Numeric calculations use binary floating point unless exact decimal-integer arithmetic is explicitly stated. No hidden measurement tolerance or decimal rounding is added; nonfinite or out-of-contract results are rejected. Numeric signed-zero results are exported as zero.

Alternative or Complementary methods

Construct a justified measurement model and complete uncertainty budget, including correlations, calibration and omitted scale/volume terms, for reliable uncertainty reporting.

References

Similar or alternative tools

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Aliquot Volume Uncertainty Term
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