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Aerosol Charge Equivalent Gap

Calculate supplied anion minus cation charge equivalents in consistent units without assigning chemical species.

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Description

Compare supplied anion and cation equivalent totals.

Gas and aerosol records need explicit species, charge, reference state, concentration and wet/dry bases. A pressure correction to mass concentration differs from a change in mole fraction, and absolute uncertainty differs from a relative percentage. Blank-corrected negative values can expose discrepancies without proving physical concentrations.

Compare supplied anion and cation equivalent totals.

When to use this tool

Use Aerosol Charge Equivalent Gap when you already have cationEquivalents, anionEquivalents and need to compare supplied anion and cation equivalent totals.

How to use the tool and how it works

  1. Enter cationEquivalents, anionEquivalents. Use the units and conventions below.
  2. Run the tool. Correct any format, range, or cross-field input error before interpreting the output.
  3. Read signedGap. Use the output convention below.

Return anionEquivalents-cationEquivalents with signs preserved.1

Input fieldMeaning and unitsAccepted input
cationEquivalentsCation EquivalentsRequired. Finite number.
anionEquivalentsAnion EquivalentsRequired. Finite number.
Output fieldInterpretationReturned shape
signedGapSigned GapRequired. Finite number.
json
{
  "input": {
    "cationEquivalents": 12,
    "anionEquivalents": 17
  },
  "output": {
    "signedGap": 5
  }
}

Limitations and assumptions

  • Both inputs need comparable unsigned charge-equivalent bases. No ions are summed, species inferred or charge-balance tolerance or aerosol composition validated.
  • Inputs must satisfy both the field types and the cross-field conditions above. Invalid input causes an error; a successful false flag or documented placeholder is a different result.
  • Numeric calculations use binary floating point unless exact decimal-integer arithmetic is explicitly stated. No hidden measurement tolerance or decimal rounding is added; nonfinite or out-of-contract results are rejected. Numeric signed-zero results are exported as zero.

Alternative or Complementary methods

Review the complete sampling, calibration and chemical analysis with verified reference conditions. Check dilution, background, charge and uncertainty definitions before using local terms in an emissions, composition or compliance assessment.

References

  1. Calculation and input contract: atmospheric-chemistry/aerosol-charge-equivalent-gap — tool.io

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